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Operando and Postreaction Diffraction Imaging of the La–Sr/CaO Catalyst in the Oxidative Coupling of Methane Reaction

Operando and Postreaction Diffraction Imaging figureOur paper on Operando and Postreaction Diffraction Imaging of the La–Sr/CaO Catalyst in the Oxidative Coupling of Methane Reaction has been published online by The Journal of Physical Chemistry.

A La–Sr/CaO catalyst was studied operando during the oxidative coupling of methane (OCM) reaction using the X-ray diffraction computed tomography technique. Full-pattern Rietveld analysis was performed in order to track the evolving solid-state chemistry during the temperature ramp, OCM reaction, as well as after cooling to room temperature. We observed a uniform distribution of the catalyst main components: La2O3, CaO–SrO mixed oxide, and the high-temperature rhombohedral polymorph of SrCO3. These were stable initially in the reaction; however, doubling the gas hourly space velocity resulted in the decomposition of SrCO3 to SrO, which subsequently led to the formation of a second CaO–SrO mixed oxide. These two mixed CaO–SrO oxides differed in terms of the extent of Sr incorporation into their unit cell. By applying Vegard’s law during the Rietveld refinement, it was possible to create maps showing the spatial variation of Sr occupancy in the mixed CaO–SrO oxides. The formation of the Sr-doped CaO species is expected to have an important role in this system through the enhancement of the lattice oxygen diffusion as well as increased catalyst basicity.

Read the full article at https://pubs.acs.org/doi/10.1021/acs.jpcc.8b09018

5D operando tomographic diffraction imaging of a catalyst bed

Our paper on 5D operando tomographic diffraction imaging of a catalyst bed has been published online by Nature Communications, volume 9, Article number: 4751 (2018)

We report the results from the first 5D tomographic diffraction imaging experiment of a complex Ni–Pd/CeO2–ZrO2/Al2O3 catalyst used for methane reforming. This five-dimensional (three spatial, one scattering and one dimension to denote time/imposed state) approach enabled us to track the chemical evolution of many particles across the catalyst bed and relate these changes to the gas environment that the particles experience. Rietveld analysis of some 2 × 106 diffraction patterns allowed us to extract heterogeneities in the catalyst from the Å to the nm and to the μm scale (3D maps corresponding to unit cell lattice parameters, crystallite sizes and phase distribution maps respectively) under different chemical environments. We are able to capture the evolution of the Ni-containing species and gain a more complete insight into the multiple roles of the CeO2-ZrO2 promoters and the reasons behind the partial deactivation of the catalyst during partial oxidation of methane.

Read the full article at https://doi.org/10.1038/s41467-018-07046-8