Figure 2. Spatial distribution of normalised scale factor (in respect to maximum value in this XRD-CT image), spatial distribution of crystallite size and lattice parameter a for CeO2 and ZrO2 collected at room temperature fresh catalyst

Work on 5D chemical imaging of an operating catalyst published

You can see the latest work from our former PhD student Dr Dorota Matras and our scientists on 5D chemical imaging in a new paper published at the Journal of Materials Chemistry A of the Royal Society of Chemistry (RSC): “Multi-length Scale 5D Diffraction Imaging of Ni-Pd/CeO2-ZrO2/Al2O3 Catalyst during Partial Oxidation of Methane.
The work was performed at ESRF in collaboration with UCL Chemistry, VITO and Boreskov Institute of Catalysis.

A 5D diffraction imaging experiment (with 3D spatial, 1D time/imposed operating conditions and 1D scattering signal) was performed with a Ni-Pd/CeO2-ZrO2/Al2O3 catalyst. The catalyst was investigated during both activation and partial oxidation of methane (POX). The spatio-temporal resolved diffraction data allowed us to obtain unprecedented insight into the behaviour and fate of the various metal and metal oxide species and how this is affected by the heterogeneity across catalyst particles. We show firstly, how Pd promotion although facilitating Ni reduction, over time leads to formation of unstable Ni-Pd metallic alloy, rendering the impact of Pd beyond the initial reduction less important. Furthermore, in the core of the particles, where the metallic Ni is primarily supported on Al2O3, poor resistance towards coke deposition was observed. We identified that this preceded via the formation of an active yet metastable interstitial solid solution of Ni-C and led to the exclusive formation of graphitic carbon, the only polymorph of coke observed. In contrast, at the outermost part of the catalyst particle, where Ni is predominantly supported on CeO2-ZrO2, the graphite formation was mitigated but sintering of Ni crystallites was more severe.

Read the full article at https://doi.org/10.1039/D1TA01464A.

 

Finden Ltd featured in ESRF highlights of 2020

We are very pleased to be featured in ESRF Highlights 2020 – their annual round-up of the most exciting experiments carried out at the ESRF in 2020. Read more on page 164 at http://www.esrf.eu/Apache_files/Highlights/2020/index.html#/page/166

Finden Ltd. to partner with University of Sheffield in new Faraday Industry Fellowship

We are looking forward to working with the University of Sheffield on the new Faraday Industry Fellowship, a collaborative energy storage research project.

This is an innovative programme that strengthens ties between battery researchers working in industry and academia.

Each fellowship enables academics and industrialists to undertake a mutually beneficial, electrochemical energy storage research project that aims to solve a critical industrial problem and that has the potential for near- and longer-term benefit to the wider UK battery industry.

We will be working to deepen the understanding of new cathode materials. The aim is to fast track the best-performing high energy density cathodes to aid their early adoption by UK industry

Read all about it at https://faraday.ac.uk/ind-fellowship-feb2021/

Neutron tomography of pistons at IMAT – ISIS Neutron and Muon Source

A team of scientists from Finden Ltd (Dr Stephen Price, Dr Simon Jacques and Prof Andrew Beale) in collaboration with Infineum UK Ltd (Dr Nathan Hollingsworth, Dr Matthew Irving) have used IMAT to help understand where and how coking occurs on engine components. This understanding will help develop more durable, fuel efficient lubricants.​​

Read the case study at https://www.isis.stfc.ac.uk/Pages/IMAT-Coking-of-engine-components.aspx

Call for applications open: The CAROTS STARTUP SCHOOL

Carots Start up School imageApply now: The CAROTS STARTUP SCHOOL offers coaching and webinars for scientists interested in discovering their entrepreneurial potential

From 1st December 2020 to 31st January 2021 scientists and engineers who work as researchers at a university or other research institution can apply for one of ten places at the CAROTS STARTUP SCHOOL. Everyone with an idea for a new Scientific Service Company based on an advanced analytical technique, for example at a large-scale research infrastructure such as a synchrotron or a neutron source or in collaboration with a university, is welcome to apply. A place at the STARTUP SCHOOL includes individual coaching sessions with some of Europe’s leading CEOs of Scientific Service Companies as well as a webinar programme teaching everything worth knowing to take the jump from scientist to entrepreneur. Participants will also get the opportunity to join a European network of likeminded people and successful scientific service companies. Online 1 to 1-coachings and monthly webinars will start in March 2021 through to June 2021.

More info: carots.eu/startup_school

New solution to the parallax problem in X-ray scattering/diffraction experiments

parallax solution with x-ray paper abstract graphicOur scientists’ new work on finding a solution to the parallax problem in X-ray scattering/diffraction experiments has been published in a new paper, “DLSR: a solution to the parallax artefact in X‐ray diffraction computed tomography data,” published in the Journal of Applied Crystallography.

The work was performed in collaboration with the creator of the TOPAS software Alan Coelho, DESY, UCL Chemistry, ESRF and SciML.

A new tomographic reconstruction algorithm is presented, termed direct least‐squares reconstruction (DLSR), which solves the well known parallax problem in X‐ray‐scattering‐based experiments. The parallax artefact arises from relatively large samples where X‐rays, scattered from a scattering angle 2gθ, arrive at multiple detector elements. This phenomenon leads to loss of physico‐chemical information associated with diffraction peak shape and position (i.e. altering the calculated crystallite size and lattice parameter values, respectively) and is currently the major barrier to investigating samples and devices at the centimetre level (scale‐up problem). The accuracy of the DLSR algorithm has been tested against simulated and experimental X‐ray diffraction computed tomography data using the TOPAS software.

This will allow upscaling chemical tomography techniques to study large samples.

Read the full article at https://doi.org/10.1107/S1600576720013576

New work on the chemical and crystallographic heterogeneities present in a Ni/NiO-YSZ solid oxide fuel cell electrode after re-oxidation

3D crystals in Solid Oxide Fuel Cell imageIn our latest work, we look with at the chemical and crystallographic heterogeneities present in a Ni/NiO-YSZ solid oxide fuel cell electrode after re-oxidation.

The research was carried out in collaboration with Dr Thomas Heenan from the Electrochemical Innovation Lab (EIL) at UCL Chemical Engineering, UCL Chemistry and ESRF.

The solid oxide fuel cell (SOFC) anode is often composed of nickel (Ni) and yttria-stabilized zirconia (YSZ). The yttria is added in small quantities (e.g., 8 mol %) to maintain the crystallographic structure throughout the operating temperatures (e.g., room-temperature to >800 °C). The YSZ skeleton provides a constraining structural support that inhibits degradation mechanisms such as Ni agglomeration and thermal expansion miss-match between the anode and electrolyte layers. Within this structure, the Ni is deposited in the oxide form and then reduced during start-up; however, exposure to oxygen (e.g., during gasket failure) readily re-oxidizes the Ni back to NiO, impeding electrochemical performance and introducing complex structural stresses. In this work, we correlate lab-based X-ray computed tomography using zone plate focusing optics, with X-ray synchrotron diffraction computed tomography to explore the crystal structure of a partially re-oxidized Ni/NiO-YSZ electrode. These state-of-the-art techniques expose several novel findings: non-isotropic YSZ lattice distributions; the presence of monoclinic zirconia around the oxidation boundary; and metallic strain complications in the presence of variable yttria content. This work provides evidence that the reduction–oxidation processes may destabilize the YSZ structure, producing monoclinic zirconia and microscopic YSZ strain, which has implications upon the electrode’s mechanical integrity and thus lifetime of the SOFC.

Read the article at https://www.mdpi.com/2073-4352/10/10/941

Our latest work on the characterisation of NMC electodes used in Li-ion batteries at the PCCP published

Multi Length Scale Chemical X-ray imaging fig

Multi Length Scale Chemical X-ray imaging on Cycled MNC Electrodes

Our latest work on the characterisation of NMC electodes used in Li-ion batteries at the PCCP has been published in a new paper, “Exploring cycling induced crystallographic change in NMC with X-ray diffraction computed tomography” in the journal Physical Chemistry Chemical Physics.

The research was carried out in collaboration with the Electrochemical Innovation Lab (EIL) from the UCL Chemical Engineering, Johnson Matthey, the Faraday Institution, NREL, UCL Chemistry and ESRF.

This study presents the application of X-ray diffraction computed tomography for the first time to analyze the crystal dimensions of LiNi0.33Mn0.33Co0.33O2 electrodes cycled to 4.2 and 4.7 V in full cells with graphite as negative electrodes at 1 μm spatial resolution to determine the change in unit cell dimensions as a result of electrochemical cycling. The nature of the technique permits the spatial localization of the diffraction information in 3D and mapping of heterogeneities from the electrode to the particle level. An overall decrease of 0.4% and 0.6% was observed for the unit cell volume after 100 cycles for the electrodes cycled to 4.2 and 4.7 V. Additionally, focused ion beam-scanning electron microscope cross-sections indicate extensive particle cracking as a function of upper cut-off voltage, further confirming that severe cycling stresses exacerbate degradation. Finally, the technique facilitates the detection of parts of the electrode that have inhomogeneous lattice parameters that deviate from the bulk of the sample, further highlighting the effectiveness of the technique as a diagnostic tool, bridging the gap between crystal structure and electrochemical performance.

Read the full article at https://doi.org/10.1039/D0CP01851A

Methane activation via integrated Membrane Reactors – project results

The results of our MEMERE project show novel membranes and catalysts reduce greenhouse gas emissions in chemical industry

The production of ethylene (C2H4) is one of the largest carbon dioxide (CO2) emitting industries in Europe. We have worked with EU-funded researchers to develop a cost-efficient, environmentally friendly process that produces higher yields than current technologies allow.

Find out more about the results at https://cordis.europa.eu/article/id/418475-novel-membranes-and-catalysts-reduce-greenhouse-gas-emissions-in-chemical-industry

Dr. Antony Vamvakeros webinar on X-ray diffraction computed tomography July 21 – available to watch online

Antony Vamvakeros webinar promo imageSynchrotron X-ray diffraction computed tomography (XRD-CT) is a marriage between powder diffraction and computed tomography using a “pencil” beam approach. The spatially-resolved signals obtained with XRD-CT can reveal information that would otherwise be lost in bulk measurements, which opens up new possibilities in functional material characterization.

In this webinar, our research scientist Dr. Antony Vamvakeros presented results from key case studies where he and the team applied XRD-CT to track the evolving solid-state chemistry of complex functional materials and devices under operating conditions. The webinar also focussed on the recent technical advances in data acquisition, treatment and handling strategies, as well as bottlenecks/limitations of the technique and the potential routes to overcome them.

For more information and to watch the webinar visit – https://www.dectris.com/landing-pages/dectris-application-webinar-series-2020/